After not really posting for a long time, I had to do this! i watch a whole bunch of TV, and I tend to focus on the romance I'm just cool that way. I also have favorite couples for every book and movie I've ever encountered, but that's not the question. And other than Ross and Rachel, I dunno who these people are. I guess I'll stick to 5 shows, as to not get excessive.

House
Chase/Cameron
House/Cuddy

Grey's Anatomy
Derrek/Meredith
Chistina/Owen
Alex/Izzy
Callie/Arizona

Charmed
Piper/Leo
Phoebe/Cole
Chris/Bianca
Paige/Kyle

Bones
Booth/Brennan

Law and Order SVU
Elliot/Olivia